General
Metals in the environment
http://www.ozestuaries.org/indicators/In_heavy_metals_f.html
NSW Environment Protection Authority
http://www.epa.nsw.gov.au/soe/soe2003/chapter5/chp_5.7.htm
Sediments are used to monitor aquatic environments because they
faithfully record and time-integrate the environmental status of
an aquatic system. Contaminant concentrations are high in
sediments, and thus they are easily, cheaply, and accurately analysed.
Sediments can be an important secondary source of pollutants, and
because they integrate contaminants over time, sediments provide
useful spatial and temporal information. Sediment quality influences
the nature of overlying and interstitial waters through physical,
chemical and biological processes. Because sediments play a major
role in the transport and storage of contaminants, they are important
in identification of contaminant sources and determining dispersion
pathways. Sediments also provide an important habitat for animals
and are a food source for many species. Sediment quality thus determines,
to a large degree, biodiversity and ecological health
in aquatic systems, and they are economically attractive in environmental
assessment of coastal environments.
From: http://www.ozestuaries.org/indicators/DEF_sediment_scheme.html
Protocol
General Water Quality Monitoring guideline (ANZECC 2000)
http://www.deh.gov.au/water/quality/nwqms/summary/chapter4.html
Surface sediments are collected as these represent recent contamination.
Only sediment consisting of a majority of fine particles are collected
as these are the ones which are physically capable of holding onto
the contaminants in question (See Case Studies). Sediment samples
are typically collected at each site using a grab, corer or other
suitably prepared sampling device (polycarbonate or stainless steel).
The contents of each grab is dumped into a polyethylene bag or pyrex
container prior to transport (in an esky) to the laboratory, where
they can be frozen (-18o C) pending analysis (for metals).
Sediment contaminant concentrations can be compared with background
data and with sediment quality criteria (ANZECC Guidelines reference),
to examine the possible hazard to aquatic organisms. Background
data can either be collected from unimpacted catchments or from
deeper sediment cores (it is assumed that deeper sediments represent
past geologic time).
The following parameters are typically analysed for in sediment
monitoring programs associated with estuarine, residential, industrial,
and rural areas.
| Metals |
Polynuclear Aromatic Hydrocarbons |
Chlorinated Hydrocarbons |
| mg/kg |
mg/kg (dry Wt) |
mg/Kg (dry Wt) |
| Ag Silver |
Naphthalene |
BHC (total) |
Al Aluminium
|
Acenaphthalene |
Aldrin |
| As Arsenic |
Acenaphthene |
Dieldrin |
| B Boron |
Fluorene |
Lindane |
| Ba Barium |
Phenanthrene |
Heptachlor |
| Bi Bismuth |
Anthracene |
Heptachlor epoxide |
| Ca Calcium |
Fluoranthrene |
DDD |
| Cd Cadmium |
Benz(a)anthracene |
DDE |
| Co Cobalt |
Chrysene |
DDT |
| Cr Chromium |
Benzol (b) & (k) fluoranthen |
a- Endosulphan Sulphate |
| Cu Copper |
Benzol (a) pyrene |
Endosulphan Sulphate |
| Fe Iron |
Indeno (1 2 3-cd) pyrene |
Chlordane |
| Hg Mercury |
Dibenz (ah) anthracene |
Methoxychlor |
| Mg Magnesium |
Benzol (ghi) perylene |
Endrin |
| Mn Manganese |
|
|
| Ni Nickel |
|
|
| Pb Lead |
|
|
| Sb Antimony |
|
|
| Se Selenium |
|
|
| V Vanadium |
|
|
| Zn Zinc |
|
|
Nutrients
| Total N |
Total P |
| mg/Kg |
mg/Kg |
Physical
| Total Inorganic Carbon |
Sediment Particle Size |
Total Organic Carbon |
| % |
%wet/dry |
Wt % |
EPA
Examples of sediment metal indicator levels
http://www.epa.nsw.gov.au/water/mwqo/proposed_mwqo.htm
Cost
Analytical costs
$6,000 for 10 sites and 13 common metals (plus sampling, labor and
reporting)
Case studies
Great Barrier Reef Marine Park Authority
http://www.gbrmpa.gov.au/corp_site/info_services/publications/misc_pub/misc_003/
Hornsby Shire Council
Estuary Manager
Berowra Creek Estuary Process Studies
E-mail: hsc@hornsby.nsw.gov.au
EPA Sydney Harbour
http://www.epa.nsw.gov.au/soe/97/ch3/13_2.htm
Person Contact
Dr Phillip Ford
CSIRO Land and Water GPO Box 1666 Canberra ACT 2601
Phone: +61 2 6246 5559
Fax: +61 2 6246 5560
Email: Phillip.Ford@csiro.au
Dr Gavin Birch, MSc, PhD, Grad.Dip.Ind.Admin
Senior Lecturer
Edgeworth David Building, Rm 510
Phone: +61 2 9351 2921
Fax: +61 2 9351 0184
Email: gavin@mail.usyd.edu.au
Web: Personal pages
Organisation contact
CSIRO
http://www.energy.csiro.au/science/environmentandgreenhouse/water_topics.htm
Advanced reference
Marine sediment monitoring
USA, Puget Sound
http://www.ecy.wa.gov/programs/eap/mar_sed/spatial.html
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