General
A pollutant load is a mass, or weight, of a chemical
entering or leaving an area, and is the product of the volume of
water that the chemical is using as its transport medium and the
concentration of the chemical in the water.
The basic load equation is:
Load (mass/time) = Concentration (mass/volume) X Flow (volume/time)
The measurement of load has the advantage over concentration in
that it can better assist the identification and help set priorities
the source of contaminants. Whereas concentration data can help
in identifying degrading processes on the environment that are independent
of flow.
Protocol
Automatic samplers are installed at either natural or constructed
portions of waterways where samples can be drawn from the creek
and the depth of water can be determined. Depth is commonly determined
by back pressure on a nitrogen bubbler. The cross sectional area
for a large range of storm events is also required to calculate
flow.
If a natural section of waterway can not be found a “V”
notch weir can be constructed which can be calibrated (cross sectional
area for flow) to the range of storm events likely to be encountered.
The tube to extract the water sample is then located behind the
weir and attached to the autosampler which is located securely on
the bank above any storm event.
Autosamplers can be of two types, or some combination. They either
take samples for later laboratory analysis or analyse samples in
situ for some common parameters such as Dissolved Oxygen, pH, Temperature,
Salinity etc.
It is recommended that at least 10 storm events of varying intensity
are sampled to determine the mean loads in wet weather. Between
5 and 10 dry weather samplings should also be included to complete
the estimation of load through time.
Autosamplers can be programmed to take samples at discrete points
of the hydrograph during a storm event or they can take a composite
sample which integrates the whole storm.
Analytes; Faecal coliforms (refrigerated sampler), Ammonical nitrogen,
Total nitrogen, Oxidised nitrogen, Total phosphorus, Filterable
phosphorus and Suspended solids
References:
Pollutant loads to Berowra Creek from Pyes, Tunks and Waitara Creeks
1995-97 for Hornsby Shire Council
By Australian Water Technologies, West Ryde, Sydney (Report No.
97/219)
Cost
Purchase Autosampler (one set) = $15,000
Installation (depending on site) = $5,000
Analysis = variable depending on parameters
By contractor = Approx. $50,000 for installation and one years
operation, including 5 dry and 5 wet weather sampling events
Case Studies
EPA Load license
http://www.epa.nsw.gov.au/licensing/lblprotocol/loadcalc-02.htm#P138_15322
Murrumbidgee River
http://eprints.anu.edu.au/archive/00000648/00/hs_wq.pdf
Person Contact
Peter Coad
Hornsby Council
pcoad@hornsby.nsw.gov.au
Advanced Reference
Load Monitoring of Lake Okeechobee, Florida
http://www.google.com.au/search?q=cache:0UHEGs-v5eoJ:fl.water.usgs.gov/PDF_files/wri97_4011_gain.pdf+water+load+monitoring&hl=en&ie=UTF-8
Chesapeak Bay River Input Monitoring Program
http://80-oh1.csa.com.ezproxy.lib.uts.edu.au/htbin/ids64/procskel.cgi
Other advanced references
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